Investigation of the elevation of saltwater wedge due to subsurface dams     

Qinpeng Chang  Tianyuan Zheng  Youyuan Chen  Xilai Zheng  Marc Walther 《水文研究》2020,34(22):4251-4261

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.  相似文献   

基于分光光度法的多量程海水营养盐原位传感器检测系统设计     

綦声波  任军博  马然  张述伟 《海洋科学》2019,43(11):76-83

针对传统海水营养盐检测方法不能满足海水营养盐长期原位监测需求的问题,研制了一种基于分光光度法的多量程海水营养盐原位传感器检测系统,通过对系统的高度集成及对多量程检测、低功耗技术、漏液保护技术的应用,实现了对海水5项营养盐参数快速、宽范围、高精度的原位测量。经过实验室和青岛中苑码头现场测试,表明本营养盐传感器检测系统具有低功耗、高可靠性能,可满足对5项营养盐参数的快速精确测量要求,实现了对海水营养盐参数的原位监测,为相关部门及时了解海洋生态环境和水体富营养化程度提供了数据支持,具有重大现实意义。  相似文献   

刘公岛海洋牧场底层海水溶解氧浓度的变化特征     

李兆钦  李欣  孙利元  刘子洲  顾艳镇  翟方国  李培良 《海洋与湖沼》2019,50(1):86-99

由于缺乏长期观测资料,前人对山东半岛邻近海域海水溶解氧的时间变化和空间分布特征的研究较少。本文基于威海刘公岛海洋牧场于2016年7月20日至2017年3月14日期间,利用生态环境实时在线观测系统获得的底层海水的温度、盐度、水深、溶解氧数据,分析了该牧场海水溶解氧浓度的时间变化特征及其影响因素,并探讨了低氧灾害发生的可能性。结果表明在观测期间,该牧场海水溶解氧浓度以季节变化为主,冬季最大、夏季最小,其中2月份平均值最高,约为10.86mg/L,8月份平均值最低,约为5.91mg/L。同时海水溶解氧浓度也存在显著的小时变化和日变化,且变化幅度于8月份最大、3月份最小。影响海水溶解氧浓度变化的主要因素是海水温度,溶解氧浓度随着温度的季节性变化而变化。夏季,水体分层会使溶解氧浓度发生大幅度的降低,大风过程对于溶解氧浓度也有一定的影响,通过打破夏季的季节性温跃层使水体发生垂向混合从而为海底提供氧气,但大风过程之后的几天会出现溶解氧浓度降低的现象。本次研究发现刘公岛海洋牧场在观测期间不存在低氧现象。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

适用于快速远程检测海水中氰化物的方法研究     

姚竞芳  袁涛  敖俊杰  顾佳媛  李佳凡 《海洋科学》2018,42(11):24-28

建立了一种适用于海洋远程快速检测氰化物的检测方法,设计了一体化检测装置,未来可搭载到无人艇上实现自动快速检测。针对最佳检测条件进行了一系列优化,得到最佳检测条件:对于100 mL的待测样品,加入酒石酸固体1.5 g;用1～2滴浓度为150 g/L的碳酸钠溶液浸润苦味酸试纸;加热温度80℃,加热时间10min。在最佳检测条件下,检测检出限达0.3mg/L。该方法实现了适用于海水氰化钠的远程检测,大大提高了检测效率,无需人员进入污染现场,安全性高。可广泛用于海洋危化品泄漏、湖泊污染、现场应急筛选等场合的水体样品快速检测。  相似文献   

Influence of a coarse interlayer on seawater intrusion and contaminant migration in coastal aquifers          下载免费PDF全文

Yi Liu  Xiaomin Mao  Jian Chen  D. A. Barry 《水文研究》2014,28(20):5162-5175

Vertical 2D slice laboratory experiments were carried out in homogenous and layered sand tanks to elucidate the effects of a highly permeable (coarse‐grained sand) interlayer on seawater intrusion and transport of contaminants to a coastal sea. Tidal fluctuations produced oscillations in the seawater–freshwater transition zone, fluctuations of the contaminant infiltration rate and a zigzag contaminant plume outline. The seawater wedge became discontinuous at the (vertical) edges of the interlayer because of increased lateral movement of the seawater–freshwater interface within the interlayer. The contaminant plume formed a tail within the interlayer depending on the tidal stage, and similar to the wedge, its movement was accentuated. A simple analytical model that neglected vertical flow reliably predicted steady‐state seawater intrusion into the coastal aquifer. Numerical modeling was used to gain insight into the groundwater hydrodynamics and contaminant migration. The numerical results confirmed the experimental findings, i.e. that a highly permeable interlayer can provide a rapid transit path for contaminants to reach the seaward boundary and that the interlayer amplifies the effects of tidal fluctuations, resulting in wider transition zones for the seawater wedge and contaminant plume. Numerical simulations further showed that, with increasing interlayer hydraulic conductivity, the maximum seawater intrusion distance inside the interlayer increases approximately linearly. For the fixed‐head contaminant injection condition used, the model showed that contaminant infiltration increases approximately logarithmically with increasing interlayer hydraulic conductivity (other factors held fixed). Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

泥水平衡盾构用海水泥浆的改性试验研究     

杨振兴  陈健  孙振川  游永锋  周建军  吕乾乾 《岩土力学》2020,41(2):501-508

由于海水中富集大量可溶性盐类及各种金属离子成分，利用海水配置的海水泥浆具有相对密度大、胶体率低、稳定性差、失水量高等特点，不能满足泥水平衡盾构施工要求。为实现对海水泥浆改性以达到利用海水泥浆维持开挖面稳定，降低穿江越海盾构施工成本，选用CMC（羧甲基纤维素钠）、纤维素PAC（聚阴离子纤维素）、聚丙烯酸铵等8种添加剂进行海水泥浆性质变化试验，优选出对海水泥浆改性明显的添加剂，并分析优选添加剂掺入量和时间对海水泥浆性质的影响规律。同时，基于优选的添加剂CMC，利用泥膜形成试验平台进行改性海水泥浆地层渗透试验。研究表明：不同添加剂对海水泥浆性质变化差异较大，增黏剂PAC、CMC对海水泥浆的改性效果稍好，24 h离析出现浑浊层、混合层、絮凝沉淀层。海水泥浆对地层渗透的滤水量大于改性海水泥浆，泥皮也稍厚，但呈稀疏状态。可以推测，添加剂中和部分海水成分，呈絮凝沉淀，多余添加剂表现出对淡水泥浆的增稠作用。  相似文献   

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt     

Basem Zoheir  Richard Goldfarb  Astrid Holzheid  Hassan Helmy  Ahmed El Sheikh 《地学前缘(英文版)》2020,11(1):325-345

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.  相似文献   

The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献